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The reaction mechanism has been investigated on the basis of a deuterium labeling experiment, mass spectrometric investigation and DFT calculation. XX is the Csences reference in the list of references.
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Gold I catalyzed cascade cyclization: The reaction proceeded through a two-fold intramolecular nucleophilic addition O-nucleophilic addition and then C aryl -nucleophilic addition to a vinylidenecyclopropane moiety to give a highly strained intermediate and subsequent retro-Diels—Alder addition.
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